首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   8347篇
  免费   660篇
  国内免费   736篇
化学   2753篇
晶体学   77篇
力学   325篇
综合类   138篇
数学   2791篇
物理学   3659篇
  2024年   17篇
  2023年   102篇
  2022年   109篇
  2021年   134篇
  2020年   150篇
  2019年   172篇
  2018年   182篇
  2017年   209篇
  2016年   253篇
  2015年   210篇
  2014年   463篇
  2013年   665篇
  2012年   545篇
  2011年   552篇
  2010年   448篇
  2009年   556篇
  2008年   597篇
  2007年   651篇
  2006年   437篇
  2005年   367篇
  2004年   352篇
  2003年   361篇
  2002年   274篇
  2001年   216篇
  2000年   230篇
  1999年   201篇
  1998年   185篇
  1997年   174篇
  1996年   184篇
  1995年   124篇
  1994年   92篇
  1993年   95篇
  1992年   66篇
  1991年   61篇
  1990年   49篇
  1989年   47篇
  1988年   42篇
  1987年   23篇
  1986年   26篇
  1985年   24篇
  1984年   17篇
  1983年   7篇
  1982年   26篇
  1981年   11篇
  1980年   7篇
  1979年   12篇
  1978年   9篇
  1976年   4篇
  1973年   1篇
  1966年   1篇
排序方式: 共有9743条查询结果,搜索用时 31 毫秒
31.
扇形换能器可以看成若干个沿孔径方向划分的均匀孔径换能器电端并联而成,根据梅森(Mason)等效电路模型以及由其延伸的混合场等效电路模型,推导出整个扇形换能器的导纳矩阵和频率响应,其中采用复阻抗模型考虑了叉指电极与自由表面的阻抗不连续的因素。本方法能够模拟指间反射、三次行程、指条寄生阻抗以及外围电路等对器件性能的影响;理论模拟与实验结果吻合。  相似文献   
32.
求线性规划初始可行基的新方法   总被引:9,自引:3,他引:6  
李炜 《运筹与管理》2004,13(1):7-10
本文提出一个求线性规划初始可行基的新算法,该算法不仅避免了人工变量,而且理论分析及初步的数值实验结果表明其效率更高。  相似文献   
33.
组合DEA方法与成熟度模型对项目效益的评价   总被引:2,自引:0,他引:2  
为全面考虑资金、管理决策能力等因素对项目效益的影响,本运用数据包络分析与项目成熟度模型结合的方法来对企业各个项目之间的相对效益进行评价,应用结果表明该评价方法对于企业资源的最优配置、提高总体效益是十分有用的。  相似文献   
34.
本利用AHP和模糊综合评价法评价物流中心选址的定性指标、用量化选址模型结合遗传算法计算定量指标,再藉助指标满意度求解把定性和定量的指标进行综合,从而为决策对物流中心选址做出科学的决策提供支持。  相似文献   
35.
In this article the main theorem establishes the necessity and sufficiency of the Poincaré-Hopf inequalities in order for the Morse inequalities to hold. The convex hull of the collection of all Betti number vectors which satisfy the Morse inequalities for a pre-assigned index data determines a Morse polytope defined on the nonnegative orthant. Using results from network flow theory, a scheme is provided for constructing all possible Betti number vectors which satisfy the Morse inequalities for a pre-assigned index data. Geometrical properties of this polytope are described.

  相似文献   

36.
n阶矩阵A称为完全正的,如果A有分解:A=BBT,其中B为元素非负矩阵,B的最小可能列数称为A的分解指数.本文考察低阶双非负矩阵在整数环上的完全正分解及其分解指数.  相似文献   
37.
The local adsorption geometry of CO adsorbed in different states on Ni(1 0 0) and on Ni(1 0 0) precovered with atomic hydrogen has been determined by C 1s (and O 1s) scanned-energy mode photoelectron diffraction, using the photoelectron binding energy changes to characterise the different states. The results confirm previous spectroscopic assignments of local atop and bridge sites both with and without coadsorbed hydrogen. The measured Ni–C bondlengths for the Ni(1 0 0)/CO states show an increase of 0.16 ± 0.04 Å in going from atop to bridge sites, while comparison with similar results for Ni(1 1 1)/CO for threefold coordinated adsorption sites show a further lengthening of the bond by 0.05 ± 0.04 Å. These changes in the Ni–CO chemisorption bondlength with bond order (for approximately constant adsorption energy) are consistent with the standard Pauling rules. However, comparison of CO adsorbed in the atop geometry with and without coadsorbed hydrogen shows that the coadsorption increases the Ni–C bondlength by only 0.06 ± 0.04 Å, despite the decrease in adsorption energy of a factor of 2 or more. This result is also reproduced by density functional theory slab calculations. The results of both the experiments and the density functional theory calculations show that CO adsorption onto the Ni(1 0 0)/H surface is accompanied by significant structural modification; the low desorption energy may then be attributed to the energy cost of this restructuring rather than weak local bonding.  相似文献   
38.
The radiation-induced decomposition of C4F9I and CF3I overlayers at 119 K on diamond (100) surfaces has been shown to be an efficient route to fluorination of the diamond surface. X-ray photoelectron spectroscopy has been used for photoactivation as well as for studying the photodecomposition of the fluoroalkyl iodide molecules, the attachment of the photofragments to the diamond surface, and the thermal decomposition of the fluoroalkyl ligands. Measured chemical shifts agree well with ab initio calculations of both C 1s and F 1s binding energies. It is found that chemisorbed CF3 groups on diamond (100) decompose by 300 K whereas C4F9 groups decompose over the range 300 to 700 K and this reactivity difference is rationalized on steric grounds. Both of these thermal decomposition processes produce surface C---F bonds on the diamond. The surface C---F species thermally decompose over a wide temperature range extending up to 1500 K. Hydrogen passivation of the diamond surface is ineffective in preventing free radical attack from the photodissociated products of the fluoroalkyl iodides; I atoms produced photolytically abstract H from surface C---H bonds to yield hydrogen iodide at 119 K allowing diamond fluorination. The attachment of chemisorbed F species to the diamond (100) surface causes band bending as the surface states are occupied as a result of chemisorption. This results in a shift to higher binding energy of the diamond-related C 1s levels present in the surface and subsurface regions which are sampled by XPS on the diamond. The use of photoactivation of fluoroalkyl iodides for the fluorination of diamond surfaces provides a convenient route compared to other methods involving the action of atomic F, molecular F2, XeF2 and F-containing plasmas.  相似文献   
39.
Linear and nonlinear optical properties of racemic (±)2-(α-methylbenzylamino)-5-nitropyridine ((±)MBANP) single crystals have been comprehensively investigated and compared with those of the enantiomorph (–)2-(α-methylbenzylamino)-5-nitropyridine ((–)MBANP) crystals. (±)MBANP crystal exhibits very high chemical and physical stability, but relatively small nonlinear optical coefficients (d31 = 6.8 pm/V, d32 = 4.7 pm/V, d33 = 0.84 pm/V). A comparison between the nonlinear optical coefficients of (±)MBANP and (–)MBANP demonstrates the validity of the oriented-gas model in molecular crystals that neglects all the contributions from intermolecular interaction.  相似文献   
40.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号